General Knowledge - Chemistry - Discussion

Discussion Forum : Chemistry - Section 1 (Q.No. 48)
48.
The molecule which has the highest percentage of ionic character among the following is
HI
HF
HCI
HBr
Answer: Option
Explanation:
No answer description is available. Let's discuss.
Discussion:
11 comments Page 1 of 2.

Fawad mustafa said:   1 decade ago
How it is possible for flourine as it is the most electronegative element in the periodictable how it ionizes easily and got highest percentage ?

T SAIRAJU said:   1 decade ago
Due to its small size & more nucleus attraction power it can attract the bond pair of electrons towards its centre and become negatively charged particle.

Anu said:   1 decade ago
Every molecule have partial ionic and covalent character. As Fluorine and Hydrogen are elements of same group, so bonding overlap will be greater & will be least for iodine. So most ionic character will be for HI due mismatch in size & larger bond length. Electronegativity can not the consider as the leading factor here.

Clint said:   1 decade ago
Iodine, as compared to fluorine and bromine, has the larger atomic radius. Since it has the larger radius, a binding hydrogen atom will be easier to be removed. Thus, creating a more ionic character in a solution.

Answer should be HI.

Rupa said:   1 decade ago
Because the electronegativity of F is more as compare to Br, Cl and I. Hence the difference between ionic character is more for HF.

Koushik said:   1 decade ago
Electronegativity series of halogens are in the manner; F>Cl>Br>I. Thus with Hydrogen the Fluorine will share the electron pair more & this is consecutively decreases down to Iodine, this makes the HF is more polar as well as ionic.

J vinayak said:   1 decade ago
Answer is HI because ionic character decreases down the group.

Pavan doma said:   10 years ago
According to FAGANS rule, for a given cation ionic nature is inversely related to size of anion.

Since fluorine is smaller in size it's ionic nature is more.

Rohit said:   9 years ago
@Vinayak.

Though ionic character decreases down the group, but it is for F, Cl, Br & I. Not for their compound with H. Thus, this can't be the reason. Instead, the difference in electronegativity of F, Cl, Br & I with H will be deciding factor as this will polarize as well as ionize the bond between them. So, order for ionic character must be HF > HCl > HBr > HI.
(2)

Ajay said:   8 years ago
Hydrogen bonding is strongest bonding. In HF there is hydrogen bonding so shows more ionic character than anyone of the above.


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