Chemical Engineering - Chemical Engineering Thermodynamics - Discussion

Discussion Forum : Chemical Engineering Thermodynamics - Section 11 (Q.No. 11)
11.
The variation of heat of reaction with temperature at constant pressure is given by the __________ law.
Kelvin's
Antonie's
Kirchoffs
none of these
Answer: Option
Explanation:
No answer description is available. Let's discuss.
Discussion:
4 comments Page 1 of 1.

Jyoti said:   5 years ago
Please anyone explain it.

Priyanka said:   4 years ago
At constant pressure, the heat capacity is equal to change in enthalpy divided by the change in temperature.

Therefore, if the heat capacities do not vary with temperature then the change in enthalpy is a function of the difference in temperature and heat capacities. The amount that the enthalpy changes by is proportional to the product of temperature change and change in heat capacities of products and reactants.

This is stated by Kirchoff's Law.

Priyanka said:   4 years ago
At constant pressure, the heat capacity is equal to change in enthalpy divided by the change in temperature.

Therefore, if the heat capacities do not vary with temperature then the change in enthalpy is a function of the difference in temperature and heat capacities. The amount that the enthalpy changes by is proportional to the product of temperature change and change in heat capacities of products and reactants.

This is stated by Kirchoff's Law.

Pawan Kumar Sharma said:   2 years ago
The variation of the heat of reaction with temperature is given by Kirchoff's equation;
(△H2−△H1)/(T2−T1)=△CP.

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