Chemical Engineering - Chemical Engineering Thermodynamics - Discussion

Discussion Forum : Chemical Engineering Thermodynamics - Section 11 (Q.No. 35)
35.
In the decomposition of PCl5 represented by, PCl5 PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5.
increase
decrease
not alter
none of these
Answer: Option
Explanation:
No answer description is available. Let's discuss.
Discussion:
3 comments Page 1 of 1.

Bhuvan said:   10 years ago
Any one can explain this problem?

Putki said:   5 years ago
According to Le-chatilier principle.

If moles of reactant < moles of product ------> forward rxn and vice versa.

Here n of reactant is lesser so forward rxn.

Negative squared said:   11 months ago
@All.

Since the mole of reactants (2) is more than the mole of the product (1), decreasing the pressure will favour the increase of the dissociation of the product.

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