Chemical Engineering - Mass Transfer - Discussion

Discussion Forum : Mass Transfer - Section 6 (Q.No. 10)
10.
Pick out the wrong statement.
Constant pressure distillation can not separate an azeotropic mixture.
Relative volatility of a binary mixture changes appreciably with the minor change in temperature.
The relative volatility of a binary mixture at azeotropic composition is unity.
Flash distillation is practised on wide spread scale in petroleum refinery.
Answer: Option
Explanation:
No answer description is available. Let's discuss.
Discussion:
2 comments Page 1 of 1.

Abhishek Mishra said:   5 years ago
Explain the answer.

Bilal said:   2 years ago
@All.

Here, the statement "Relative volatility of a binary mixture changes appreciably with the minor change in temperature" is true.

Even a small change in temperature can have a significant effect on the relative volatility of a binary mixture. This is because the vapor pressure and hence the relative volatility of the components are temperature dependent, and even a minor change in temperature can result in a significant change in vapor pressure and relative volatility. As a result, distillation processes that rely on relative volatility for separation are very sensitive to changes in temperature.
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