Chemical Engineering - Chemical Engineering Thermodynamics - Discussion

Discussion Forum : Chemical Engineering Thermodynamics - Section 5 (Q.No. 49)
49.
If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as
solubility increases as temperature increases.
solubility increases as temperature decreases.
solubility is independent of temperature.
solubility increases or decreases with temperature depending on the Gibbs free energy change of solution.
Answer: Option
Explanation:
No answer description is available. Let's discuss.
Discussion:
1 comments Page 1 of 1.

Pawan Kumar Sharma said:   2 years ago
The effect of temperature on the solubility of a gas in a liquid:

According to Charles's law, the volume of a given mass of a gas increases with an increase in temperature. The volume of a given mass of dissolved gas in solution also increases with the increase in temperature. It becomes impossible for the solvent to accommodate gaseous solute in it and gas bubbles out.

Hence, with an increase in temperature, the solubility of a gas in a liquid decreases.

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